This work reports a numerical investigation of the transient operation of a 100-kWth solar reactor for performing the high-temperature step of the Zn/ZnO thermochemical cycle. This two-step redox cycle comprises (1) the endothermal dissociation of ZnO to Zn and O2 above 2000 K using concentrated solar energy, and (2) the subsequent oxidation of Zn with H2O/CO2 to produce H2/CO. The performance of the 100-kWth solar reactor is investigated using a dynamic numerical model consisting of two coupled submodels. The first is a Monte Carlo (MC) ray-tracing model applied to compute the spatial distribution maps of incident solar flux absorbed on the reactor surfaces when subjected to concentrated solar irradiation delivered by the PROMES-CNRS MegaWatt Solar Furnace (MWSF). The second is a heat transfer and thermochemical model that uses the computed maps of absorbed solar flux as radiation boundary condition to simulate the coupled processes of chemical reaction and heat transfer by radiation, convection, and conduction. Experimental validation of the solar reactor model is accomplished by comparing solar radiative power input, temperatures, and ZnO dissociation rates with measured data acquired with the 100-kWth solar reactor at the MWSF. Experimentally obtained solar-to-chemical energy conversion efficiencies are reported and the various energy flows are quantified. The model shows the prominent influence of reaction kinetics on the attainable energy conversion efficiencies, revealing the potential of achieving ηsolar-to-chemical = 16% provided the mass transport limitations on the ZnO reaction interface were overcome.
Issue Section:
Research Papers
Keywords:
Chemistry,
Energy,
Heat transfer,
Mass Transfer,
Optics,
Solar,
Solar reactor,
Solar receiver
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