Prismatic elements are widely used in daylight illumination systems. The characteristics of the light that emerges from the surface of a right-angled prism vary with the apex of the prism and the incident angle of the sunshine illuminating the surface of the prismatic daylight collector. This paper investigates the effect of the apex angle of a right-angled prismatic collector on the performance of the collector using a matrix ray-tracing model and the edge principle. It was found that the majority of the light emerges from the hypotenuse of the right-angled prism when sunshine is incident on the surface of the prismatic daylight collector; furthermore, the flux of the light emerging from the hypotenuse that directs illuminating space decreases as the apex of the right-angled prism is increased. The intensity distribution of the majority of the light emerging from the hypotenuse of a right-angled prism can be used to guide the design of natural light illumination systems and enhance their performance. The percentage of light emerging from the hypotenuse decreases with the number of prismatic elements because the relative area of the emerging light that reaches the adjacent prism increases with the number of prismatic elements. The analysis of the relative area of the hypotenuse, where the emerging light that reaches the adjacent prism according to the edge ray principle shows that the total area is constant when the number of prismatic elements is greater than 10; an economical prismatic daylight collector can be realized with less material due to the larger number of smaller prisms with the same apex.